化学
沸石
水热合成
热液循环
ZSM-5型
丁醇
化学工程
铵
分解
酒
有机化学
乙醇
催化作用
工程类
作者
Tatsushi Yoshioka,Zhendong Liu,Kenta Iyoki,Tsuneji Sano,Mariko Ando,Sohei Sukenaga,Hiroyuki Shibata,Tatsuya Okubo,Toru Wakihara
出处
期刊:Chemistry Letters
[Oxford University Press]
日期:2020-09-05
卷期号:49 (9): 1006-1008
被引量:5
摘要
Hydrothermal stability and productivity of zeolite are important concerns when considering its industrial applications. In this study, we used 1-butanol as an organic additive for the synthesis of ZSM-5, which resulted in rapid synthesis within 2 h. The fully crystalline product was proved to possess fewer structural defects, and higher hydrothermal stability. We have successfully demonstrated a rapid synthesis route for ZSM-5 zeolite without quaternary ammonium cations, but with 1-butanol as an organic additive. The employment of the alcohol enabled synthesis at higher temperatures, resulting in rapid synthesis within 2 h, as well as high hydrothermal stability of zeolite crystals due to fewer structural defects.
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