铜
八面体
四氟硼酸盐
化学
结晶学
三唑
Atom(片上系统)
金属
平方(代数)
立体化学
晶体结构
几何学
有机化学
数学
离子液体
计算机科学
嵌入式系统
催化作用
作者
A.M. Mills,K. Flinzner,A.F. Stassen,Jaap G. Haasnoot,Anthony L. Spek
标识
DOI:10.1107/s0108270102003086
摘要
In the title complex, [Cu(BF(4))(2)(1tpc)(4)] [1tpc is 1-(3-chloropropyl)-1,2,4-triazole, C(5)H(8)ClN(3)], the copper(II) centres reside in a tetragonally distorted octahedral coordination environment. Four 1tpc ligands are coordinated to the metal atom via the N4 atom of the triazole rings in a square-planar arrangement, with Cu-N bond lengths in the range 2.002 (2)-2.019 (2) A. Two tetrafluoroborate anions, in the axial positions above and below the square plane, are weakly coordinated to the copper(II) centre, with Cu-F distances of 2.4009 (18) and 2.5096 (18) A.
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