砷
土壤水分
浸出(土壤学)
化学
标准物质
试剂
萃取(化学)
溶解
环境化学
环境科学
土壤科学
色谱法
检出限
物理化学
有机化学
作者
Christine Gleyzes,S. Tellier,R. Sabrier,M. Astruc
标识
DOI:10.1080/09593332208618313
摘要
The purpose of this research was to find a reliable and easy to use method to characterise As in iron-rich industrial or mining site soils. In this objective classical sequential extraction schemes and single extractions with EDTA and phosphate solutions were used. Results showed that classical Tessier's scheme overestimated residual As. A scheme specific to anionic species was also not really suitable to evaluate As distribution in these iron-rich soils. A more complex scheme using specific iron reagents indicated a correlation between iron dissolution and arsenic leaching and these results were confirmed by single extractions with EDTA and oxalate solutions. Finally a simplified and less time consuming scheme was established, tested on diverse industrial soils and validated on a certified sediment reference material. It allowed evaluation in 24 hours of the easily extractable fraction, amount solubilized under reducing conditions and As strongly bound to the soil.
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