Organic Photovoltaics with Multiple Donor–Acceptor Pairs

Compared with conventional organic solar cells (OSCs) based on single donor-acceptor pairs, terpolymer- and ternary-based OSCs featuring multiple donor-acceptor pairs are promising strategies for enhancing the performance while maintaining an easy and simple synthetic process. Using multiple donor-acceptor pairs in the active layer, the key photovoltaic parameters (i.e., short-circuit current density, open-circuit voltage, and fill factor) governing the OSC characteristics can be simultaneously or individually improved by positive changes in light-harvesting ability, molecular energy levels, and blend morphology. Here, these three major contributions are discussed with the aim of offering in-depth insights in combined terpolymers and ternary systems. Recent exemplary cases of OSCs with multiple donor-acceptor pairs are summarized and more advanced research and perspectives for further developments in this field are highlighted.