催化作用
热解
纤维素
选择性
化学
质谱法
气相色谱法
碳氢化合物
核化学
有机化学
色谱法
作者
Wenbin Li,Jida Wang,Zhen Wang,Jie Chen,Xiaoan Nie,Zhangshuai Ding,Dechao Wang,Dechao Wang,Yunwu Zheng,Jianchun Jiang
标识
DOI:10.1016/j.joei.2021.06.014
摘要
Pt–Sn–Ce/γ-Al2O3 catalysts were synthesized by the impregnation method and used to produce aromatic hydrocarbons (AHs)-rich bio-oil via catalytic fast pyrolysis of cellulose. The upgraded products were on-line analyzed by pyrolysis-comprehensive two-dimensional gas chromatography/mass spectrometry (Py-GC × GC/MS). It was found that Pt–Sn–Ce/γ-Al2O3 catalysts were effective for improving the relative content of AHs in bio-oil. Especially, Pt–Sn–Ce/γ-Al2O3 contributed the highest AHs content (85.82%), which was 3 times than that of γ-Al2O3, and increased 85.44% compared with non-catalytic. In addition, Pt–Sn–Ce/γ-Al2O3 and Pt–Sn/γ-Al2O3 can generate the highest monocyclic aromatic hydrocarbons (MAHs) with the relative content of 60.24% and 51.92%, respectively. Pt–Sn–Ce/γ-Al2O3 catalyst can be reused five times with stable catalytic activity to produce AHs-rich bio-oil.
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