Effective hydrogen isotope separation by a robust flexible calix[4]resorcinarene-based porous organic cage

Herein, we present the design and synthesis of a new [6+12] octahedral-type porous organic cage (POC), namely CPOC-F301, assembled from 6 bowl-shaped tetraformylcalix[4]resorcinarene and 12 flexible trans-1,4-cyclohexanediamine. This cage exhibits...