阴极
材料科学
钾
氧化还原
双层
储能
离子
化学工程
动力学
电化学
纳米技术
作者
Jiaxin Hao,Hang Xia,Apparao M. Rao,Yongmin He,Jiang Zhou,Bingan Lu
标识
DOI:10.1016/j.ensm.2022.08.051
摘要
Potassium-ion batteries are gaining interest as grid-scale energy storage devices due to their abundant potassium sources and low cost. However, the large size K + ions (1.3 Å) cause severe structural damage to the host materials, leading to limited lifespan. Here, an ultra-stable potassium cathode composed of single-bilayer V 2 O 5 is prepared, exhibiting high capacity (132 mAh g −1 ), excellent rate capability (8 A g −1 ) and durable lifetime of over 9000 cycles. Our kinetics and theoretical analyses revealed that the all-surface-state K storage capability of single-bilayer V 2 O 5 is responsible for such exceptional cathode performance. It enables easy access for K + ions to redox sites and permits rapid redox kinetics with negligible effect on the crystal structure. By pairing the cathode with pre-potassiated graphite, the full cell achieved a capacity retention of up to 83% after 400 cycles. The study establishes a new insight into host design for durable potassium cathode.
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