储能
氧化还原
电池(电)
电化学储能
流动电池
有机自由基电池
纳米技术
锂(药物)
电解质
能量密度
模块化设计
电化学
化学
材料科学
工艺工程
计算机科学
工程物理
超级电容器
功率(物理)
电极
无机化学
工程类
物理
物理化学
内分泌学
操作系统
医学
量子力学
作者
Yu Zhao,Yu Ding,Yutao Li,Lele Peng,Hye Ryung Byon,John B Goodenough,Guihua Yu
摘要
Electrical energy storage system such as secondary batteries is the principle power source for portable electronics, electric vehicles and stationary energy storage. As an emerging battery technology, Li-redox flow batteries inherit the advantageous features of modular design of conventional redox flow batteries and high voltage and energy efficiency of Li-ion batteries, showing great promise as efficient electrical energy storage system in transportation, commercial, and residential applications. The chemistry of lithium redox flow batteries with aqueous or non-aqueous electrolyte enables widened electrochemical potential window thus may provide much greater energy density and efficiency than conventional redox flow batteries based on proton chemistry. This Review summarizes the design rationale, fundamentals and characterization of Li-redox flow batteries from a chemistry and material perspective, with particular emphasis on the new chemistries and materials. The latest advances and associated challenges/opportunities are comprehensively discussed.
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