生物分子
电催化剂
电化学气体传感器
电化学
催化作用
化学
纳米技术
材料科学
电极
有机化学
物理化学
作者
Yu Zhang,Hengjia Wang,Lei Jiao,Nannan Wu,Weiqing Xu,Zhichao Wu,Yu Wu,Peng Hu,Wenling Gu,Chengzhou Zhu
标识
DOI:10.1016/j.cej.2023.143075
摘要
Reasonable design and construction of high-performance catalysts are desirable for improving the sensitivity of electrochemical sensors, but still remain a great challenge. Herein, ultrathin PdMo metallene with defects (D-PdMo) is fabricated and employed as an electrocatalyst to construct electrochemical sensors for the sensitive determination of small biomolecules. Taking advantage of the change of electronic structure, conductivity and electrochemical active surface areas caused by the defect engineering, the resultant D-PdMo metallene exhibits a much better electrocatalytic ability to dopamine (DA) than PdMo metallene. Furthermore, the proposed electrochemical sensor realizes sensitive DA detection in human blood serum and cells. Our work not only verifies the feasibility of introducing defects into metallene to enhance catalytic performance but also broadens the application of metallene in the electrochemical sensors for monitoring biomolecules in living organisms.
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