阳极
电化学
锂(药物)
硅
材料科学
石墨
表面改性
电解质
阴极
纳米技术
化学工程
电极
化学
光电子学
复合材料
工程类
医学
物理化学
内分泌学
作者
Yaxin Feng,Yang Zhang,Ye Song,Pingyun Li,Jie Liu
标识
DOI:10.1002/slct.202204086
摘要
As the research on lithium-ion battery cathode materials gradually breaks through the saturation, the anode materials for lithium-ion batteries have received wide attention because of their promising future. Silicon electrodes, in particular, are attracting increasing attention. In this paper, the Si/G precursor was achieved by simple mechanical ball milling. Two silicon based composite electrode materials [email protected] and [email protected] were synthesized by spontaneous polymerization of tannic acid on precursor surface in Tris buffer solution. For the poor electrical conductivity of silicon, graphite was added as a carbon source to avoid the direct contact between silicon and electrolyte during charge/discharge process by forming tannic acid coating on silicon surface.The [email protected] composites achieve a discharge specific capacity of 927.4 mAh g−1 at 100 mA g−1 current density after 50 cycles with a retention rate of 87.1 % while the reversible capacity of [email protected] is 1249.8 mAh g−1 with a retention rate is 93.6 %. This unique composite method provides new insights into the modification of silicon anode materials.
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