膜
催化作用
阴极
化学工程
功率密度
碱性燃料电池
膜电极组件
材料科学
铂金
电流密度
离子交换
制作
燃料电池
图层(电子)
电极
分解水
纳米技术
化学
离子
功率(物理)
有机化学
阳极
物理化学
工程类
医学
替代医学
光催化
量子力学
生物化学
病理
物理
作者
Chang Liu,Tianyue Gao,Leanna Schulte,Sariah Marth,Heemin Park,Chulsung Bae,Thomas E. Mallouk
出处
期刊:ACS energy letters
[American Chemical Society]
日期:2024-12-23
卷期号:10 (1): 420-426
被引量:3
标识
DOI:10.1021/acsenergylett.4c02824
摘要
Alkaline exchange membrane fuel cells (AEMFCs) offer a promising solution for clean hydrogen utilization. However, effective water management remains a challenge due to the concurrent generation and consumption of water at the electrodes, which impacts the efficiency of AEMFCs at high current densities. Here, we report the fabrication of alkaline fuel cells with improved water management by employing a three-dimensionally patterned alkaline exchange membrane (AEM) at the interface with the cathode catalyst layer. This micropatterned AEM, made by soft lithography, enables a power density of 628 mW cm–2 at a current density of 1100 mA cm–2, representing an approximately 50% performance improvement over identical AEMFCs made from conventional two-dimensional AEMs. The patterned AEM also improves platinum utilization due to the increased catalyst-membrane contact area and tailored catalyst layer thickness.
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