NASICON lithium ions conductors: Materials, composites, and batteries

In this review, we present the most recent studies about NASICON (LATP, LAGP, LZP) solid electrolytes in Li-metal batteries and show possible structure evolutions and their applications in polymer composites as membranes electrolyte. We describe all the possible interfacial side reactions occurring at the cathode and the lithium (Li) metal electrodes and summarize the possible options that have been proposed in the literature to date to suppress these reactions.