均分解
替代(逻辑)
亲电芳香族取代
化学
分子内力
生化工程
组合化学
计算机科学
有机化学
激进的
工程类
程序设计语言
作者
W. Russell Bowman,John M. D. Storey
摘要
This critical review aims at presenting recent developments in intramolecular aromatic homolytic substitution which has become one of the common methodologies in modern synthesis. The application of Bu3SnH-mediated cyclisations have proved especially useful. The critical review illustrates the mechanistic considerations required for planning synthetic applications and a wide range of synthetic protocols and natural product syntheses are shown. The latest evidence for the mechanisms involved in aromatic homolytic substitution are presented. (152 references).
科研通智能强力驱动
Strongly Powered by AbleSci AI