Metal organic framework derived one-dimensional porous Fe/N-doped carbon nanofibers with enhanced catalytic performance

The aggregation of metal nanoparticles and collapse of precursor metal organic frameworks (MOFs) structure during the carbonization process largely hamper the catalytic performance of MOFs-derived carbon catalysts. Here, we report hollow and porous one-dimensional Fe/N-doped carbon nanofibers (Fe/NCNFs) for activating peroxymonosulfate (PMS), which was obtained by immobilizing Fe-MIL-101 on polyacrylonitrile (PAN) nanofibers via electrospinning technique followed by pyrolysis. The presence of one-dimensional PAN channel suppresses the agglomeration tendency of metal particles during the carbonisation process of Fe-MIL-101, resulting in a uniform dispersion of nanoparticles and an increase of catalytic active sites. The resultant Fe/NCNFs-9 possesses unique hierarchical architecture, large active surface area, well-dispersed Fe species, and abundant Fe-N active sites. These superiorities contributed to the better catalytic performance of Fe/NCNFs-9 compared with PAN derived carbon (PAN-C-9) and Fe-MIL-101 derived carbon (Fe-C-9). Through a series of inhibitor experiments and electrochemical tests, the radical pathway is dominant on BPA removal with the participation of the non-radical pathway in the multi-sites Fe/NCNFs-9/PMS/BPA system. Surprisingly, this strategy could successfully disperse Fe species and effectively reduce the Fe leaching. This work supplies a novel method to design efficient MOFs-derived carbon catalysts toward micropollutants removal.