脱氢
丙烷
金属间化合物
产量(工程)
催化作用
选择性
热力学
化学
材料科学
热力学平衡
无机化学
冶金
有机化学
物理
合金
作者
Jianshuo Zhang,Ruoyun Ma,Hyungwon Ham,Ken‐ichi Shimizu,Shinya Furukawa
出处
期刊:JACS Au
[American Chemical Society]
日期:2021-08-31
卷期号:1 (10): 1688-1693
被引量:28
标识
DOI:10.1021/jacsau.1c00287
摘要
catalyst gave a propylene yield of 10.2% with high selectivity, even at 250 °C, where the thermodynamic equilibrium yield was only 0.15%. Electroassisted proton collisions with propane allowed an unusual reaction pathway for low-temperature PDH. Alloying of Pt with In drastically enhanced the activity and selectivity due to the increased electron density of Pt.
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