High-nitrogen energetic materials derived from azotetrazolate

Abstract The preparation and properties of three unique high-nitrogen materials based on the anion azotetrazolate are described. Cations examined were the ammonium, guanidinium and triaminoguanidinium. These compounds are unique in their gas generating ability with little or no smoke or residue produced. These materials have possible applications as explosives, pyrotechnics, gas generants and low signature propellants.