化学
无水的
烯烃纤维
催化作用
结合
烷基化
水溶液
配体(生物化学)
水介质
组合化学
药物化学
有机化学
数学
生物化学
数学分析
受体
作者
Zhong‐Ming Sun,Jing Zhang,Rajith S. Manan,Pinjing Zhao
摘要
Assisted by a partially aqueous media, a catalyst system of [Rh(cod)(OH)](2) and DPPBenzene ligand effectively promotes direct conjugate additions by perfluoroarenes. This formal C-H alkylation process represents a rare example of olefin hydroarylation with electron-deficient arenes. The catalyst system can be modified to selectively form the corresponding olefination products under anhydrous conditions.
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