己内酰胺
己内酯
化学
可再生能源
可再生资源
催化作用
选择性
有机化学
尼龙6
制浆造纸工业
聚合
聚合物
工程类
电气工程
作者
Teddy Buntara,S. Noël,Pim Huat Phua,Ignacio Melián‐Cabrera,Johannes G. de Vries,Hero J. Heeres
标识
DOI:10.1002/anie.201102156
摘要
Renewable nylon: 5-Hydroxymethylfurfural (HMF), which can be obtained from renewable resources such as D-fructose, was converted into caprolactone with very good overall selectivity in only three steps. The new route involves two hydrogenation steps to obtain 1,6-hexanediol, which was oxidatively cyclized to caprolactone, and then converted into caprolactam.
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