Facile Dimension Transformation Strategy for Fabrication of Efficient and Stable CsPbI3 Perovskite Solar Cells

All-inorganic cesium lead triiodide (CsPbI₃) perovskite has received increasing attention due to its intrinsic thermal stability and suitable band gap for photovoltaic applications. However, it is difficult to deposit high-quality pure-phase CsPbI₃ films using CsI and PbI₂ as precursors due to the rapid nucleation and crystal growth by the solution coating method. Here, a simple cation-exchange approach is employed to fabricate all-inorganic 3D CsPbI₃ perovskite, where 1D ethylammonium lead (EAPbI₃) perovskite is first solution-deposited and then transformed to 3D CsPbI₃ via ion exchange between EA⁺ and Cs⁺ during thermal annealing. The large space between the PbI₃^- skeletons in 1D EAPbI₃ favors the cation interdiffusion and exchange for the formation of pure-phase 3D CsPbI₃ with full compactness and high crystallinity and orientation. The resulting CsPbI₃ film exhibits a low trap density of state and high charge mobility, and the perovskite solar cell shows a power-conversion efficiency of 18.2% with enhanced stability. This strategy provides an alternative and promising fabrication route for the fabrication of high-quality all-inorganic perovskite devices.