Advances in anion-intercalated layered double hydroxides for supercapacitors: study of chemical modifications and classifications

Hybrid material-based electrochemical supercapacitors (SCs) possessing improved energy density (ED), enhanced stability, high porosity, and a large accessible surface area have attracted attention as promising energy storage devices. SCs also demonstrate excellent specific capacitance (C_s) across various current densities, increased capacitance, and high cell voltages, all contributing to improved ED. Layered double hydroxides (LDHs), with their anionic exchange capabilities and laminar structures, offer significant potential for boosting charge transfer in SCs. This review provides a comprehensive overview of the recent advances in anion-based LDHs, discussing their storage mechanisms, chemical modifications, and classification based on interlayer anions. The roles of different anions, including monovalent, divalent, and polyoxometalates, in enhancing storage properties are examined. In addition, the challenges, future research directions, and practical perspectives of anion-storing LDHs are presented. Hence, this review provides a concise overview of anion-based LDHs for SCs, highlighting their potential significance in energy storage applications.