木质素
吸附
海绵
化学工程
材料科学
热稳定性
光催化
复合数
己烷
辐照
核化学
化学
有机化学
复合材料
催化作用
植物
物理
核物理学
工程类
生物
作者
Guo Zhang,Mingkun Wang,Lei Qiao,Jianxiang Wang,Zhiwei He
出处
期刊:Langmuir
[American Chemical Society]
日期:2023-11-16
卷期号:39 (47): 16935-16953
被引量:3
标识
DOI:10.1021/acs.langmuir.3c02810
摘要
Frequent oil spills and the discharge of industrial oily wastewaters have become a serious threat to the environment, ecosystem, and human beings. Herein, a photothermal, magnetic, and superhydrophobic PU sponge decorated with a Fe3O4/MXene/lignin composite (labeled as S-Fe3O4/MXene/lignin@PU sponge) has been designed and prepared. The obtained superhydrophobic/superoleophilic PU sponge possesses excellent chemical stability, thermal stability, and mechanical durability in terms of being immersed in corrosive solutions and organic solvents and boiling water and being abrased by sandpapers, respectively. The oil adsorption capacities of the S-Fe3O4/MXene/lignin@PU sponge for various organic liquids range from 29.1 to 70.3 g/g, and the oil adsorption capacity for CCl4 can remain 69.6 g/g even after 15 cyclic adsorption tests. The separation efficiencies of the S-Fe3O4/MXene/lignin@PU sponge for n-hexane and CCl4 are higher than 98% in different environments (i.e., water, hot water, 1 mol/L NaOH, 1 mol/L NaCl, and 1 mol/L HCl). More importantly, the introduction of three light absorbers (i.e., Fe3O4, MXene, and lignin) into the S-Fe3O4/MXene/lignin@PU sponge shows a synergistic effect in the photothermal heat conversion performance, and the maximum surface temperature reaches 64.4 °C under sunlight irradiation (1.0 kW/m2). The separation flux of the S-Fe3O4/MXene/lignin@PU sponge for viscous LT147 vacuum pump oil reaches 35,469 L m-2 h-1 under sunlight irradiation, showing an increase of 27.3% compared to that of oil adsorption processes without the photothermal effect. Thus, the rational design of superhydrophobic sponges by introducing proper photothermal heat absorbers provides new insights into facile and cost-effective preparation of sponges for efficient oil/water separation.
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