Co-vitrification of municipal solid waste incinerator fly ash and bottom slag: Glass detoxifying characteristics and porous reformation

Safety and efficient dispose of municipal solid waste incineration (MSWI) fly ash with high toxicity has emerged as a worldwide challenge. Vitrification provides the advantages of capacity reduction, detoxification, and solidification of heavy metals, which has the potential to dispose of hazardous waste on a large scale. Herein, co-vitrification of MSWI fly ash and bottom slag has been accomplished based on the characteristics of calcium and silicon composition. A novel approach for producing glass ceramic foams by alkaline activation-crystallization was developed to realize the disposal of the obtained glass. The effect of MSWI fly ash/bottom slag ratios on the glass network, crystallization ability of the basic glass, pore structure, and physical properties of the porous green body was investigated. The results revealed that with increasing MSWI fly ash proportion, the Si-O of [SiO₄] in the basic glass changed significantly and the crystallization ability steadily reduced. Si-O and Al-O in basic glass are easy to corrode under alkaline conditions, releasing Ca²⁺ and forming a low solubility product, calcium silicate hydrate. When the crystallization temperature increases from 950 ℃ to 1150 ℃, it is more conducive to the precipitation of the gehlenite phase. Extending the crystallization time promotes three-dimensional growth of crystals that are coupled with each other to form a network structure and a multi-stage pore structure. The pore structure was developed with the help of NH₃ and H₂ generated by the secondary aluminum ash (SAA). Through the preparation of glass ceramic foams, the raw materials were detoxified. The toxic heavy metals showed extremely low leaching concentrations, which were smaller than the limit of TCLP. The prepared samples had 70.22-80.61% of porosity, 0.78-1.19 g/cm³ of low bulk density, and 0.54-7.86 MPa of compressive strength.