分子
质子
金属有机骨架
图层(电子)
材料科学
镍
金属
电导率
纳米尺度
质子输运
化学物理
化学工程
纳米技术
物理化学
化学
吸附
有机化学
物理
量子力学
工程类
冶金
作者
Yang Cui,Dongyang Li,Zhichao Shao,Yujie Zhao,Kangshuai Geng,Jing Huang,Yatao Zhang,Hongwei Hou
出处
期刊:Small
[Wiley]
日期:2023-11-27
标识
DOI:10.1002/smll.202307964
摘要
The directional arrangement of H2 O molecules can effectively regulate the ordered protons transfer to improve transport efficiency, which can be controlled by the interaction between materials and H2 O. Herein, a strategy to build a stable hydration layer in metal-organic framework (MOF) platforms, in which hydrophilic centers that can manipulate H2 O molecules are implanted into MOF cavities is presented. The rigid grid-Ni-MOF is selected as the supporting material due to the uniformly distributed cavities and rigid structures. The Ag0 possesses potential combination ability with the hydrophilic substances, so it is introduced into the MOF as hydration layer centers. Relying on the strong interaction between Ag0 and H2 O, the H2 O molecules can rearrange around Ag0 in the cavity, which is intuitively verified by DFT calculation and molecular dynamics simulation. The establishment of a hydration layer in Ag@Ni-MOF regulates the chemical properties of the material and gives the material excellent proton conduction performance, with a proton conductivity of 4.86 × 10-2 S cm-1 .
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