煤
无烟煤
煤炭能源价值
化学
自燃
燃烧
极限氧浓度
氧气
煤燃烧产物
强化煤层气回收
煤矿开采
废物管理
有机化学
工程类
作者
Tong-Shuang Liu,Wei-le Chen,Yongjun He,Jun Deng,Caiping Wang,Hao-Jia Li
标识
DOI:10.1080/00102202.2024.2320681
摘要
The coexistence of gas and spontaneous coal combustion poses a serious threat to mine production safety. Therefore, studying the compound disaster of gas and spontaneous coal combustion and revealing the impact of gas concentration on the characteristic parameters of coal spontaneous combustion are of great significance for understanding the mechanism of compound disasters involving coal and gas and for comprehensive management. Based on theoretical analysis, this paper selects four typical types of cannel coal、non-caking coal、meager coal、anthracite coal as research subjects, and conducts programmed heating experiments on coal samples under different gas concentration conditions, aiming to provide a theoretical basis for the prevention and control of spontaneous coal combustion in a gas environment. Experimental results show that with the increase in temperature of the coal samples, the oxygen consumption rate and heating emission intensity exhibit a trend of slow increase followed by rapid increase. With the increase in gas concentration in the environment, the production of CO and CO2, oxygen consumption rate, and heat emission intensity of coal spontaneous combustion all show a decreasing trend. This is mainly because the high gas concentration occupies the adsorption sites on coal molecules, thereby hindering the reaction between coal and oxygen. Additionally, by calculating the thermodynamic parameters of the coal samples, it was found that the apparent activation energy increases with the increase in gas concentration, further confirming that the increase in gas concentration in the environment significantly inhibits the spontaneous combustion process of coal.
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