材料科学
色度
探测器
猝灭(荧光)
荧光粉
光致发光
热稳定性
热的
信号(编程语言)
光电子学
光纤
热释光
兴奋剂
电流(流体)
光电探测器
纳米技术
理论(学习稳定性)
发光
可见光谱
光热治疗
光学
荧光
作者
Qianyi Chen,Dongdan Chen,Pan Zheng,Zhenjie Lun,Jianming Yuan,Yongsheng Sun,Haojun Liu,Shanhui Xu,Zhongmin Yang
标识
DOI:10.1002/adma.202513743
摘要
Abstract The development of stable and precise visible light sources is crucial for advanced cellular analysis, yet current spectrophotometric systems face significant challenges, particularly temperature‐dependent signal drift and decreased measurement accuracy. In this work, a novel yellow‐emitting phosphor Gd 3 ScGa 4 O 12 : Dy 3+ is developed, which demonstrates exceptional thermal stability with zero‐thermal quenching (ZTQ) up to 200 °C. This remarkable performance is achieved through the strategic manipulation of trap‐assisted thermoluminescence enhancement mechanisms. In addition, a flexible optical detector is developed for oxyhemoglobin (HbO 2 ) concentration testing by incorporating Gd 3 ScGa 4 O 12 : Dy 3+ in stretchable elastomer‐based optical fiber. The fabricated device exhibits exceptional photoluminescence stability (near‐zero chromaticity drift, Δx/y < 0.003 from 10 to 40 °C), and promising measurement accuracy (200 µg mL −1 ). Tb 3+ / Eu 3+ / Pr 3+ doped Gd 3 ScGa 4 O 12 is also developed, which all perform favorable thermal stability. This finding not only provides a reliable and reusable cellular concentration detector but also establishes a ZTQ design framework for lanthanide‐doped materials.
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