Highly Efficient Photocatalytic Degradation of Tetracycline by Modifying UiO-66 via Different Regulation Strategies

Wastewater containing organic pollutants cause potential harm to the environment and human health. A series of zirconium-organic frameworks (UiO-66) and their composites were synthesized by solvothermal methods, including band gap adjustment, heterojunction construction, and metal ion doping. For the model pollutant tetracycline (TC), all of the prepared catalysts could achieve effective degradation of it. Therein, the degradation efficiency of tetracycline could reach 95% under the UV irradiation with the aid of the catalyst, in which the UiO-66-NDC was modified with P–C3N4. The free radical capture experiments demonstrated that the superoxide radical (•O2–) was the main oxidizing species for the photodegradation of tetracycline. Hence, the improvement strategy of the catalyst would provide some enlightenment for the development of more efficient photocatalysts for the degradation of organic dyes in wastewater.