黑磷
介孔材料
基质(水族馆)
复合数
材料科学
磷
纳米技术
化学工程
化学
复合材料
冶金
有机化学
光电子学
催化作用
地质学
工程类
海洋学
作者
Danni Xue,Jing Tang,J. Zhang,Huan Liu,Chenjie Gu,Xingfei Zhou,Tao Jiang,Lei Shi
标识
DOI:10.1016/j.apsusc.2024.160001
摘要
Semiconductor-based surface-enhanced Raman scattering (SERS) dependent on chemical mechanism has shown favorable selective enhancement and recognition capabilities. However, the limited Raman enhancement capability of conventional semiconductor-based still remains a great challenge in the effective monitoring of trace molecules in a practical complex environment. In this context, a novel two-dimensional composite semiconductor substrate was developed by in-situ growing reticular ZIF-67 mesoporous film upon black phosphorus (BP) nanosheets. An attractive synergistic chemical enhancement was triggered attributed to the efficient continued charge transfer process in the BP/ZIF-67 system. Particularly, a selective SERS enhancement of food additive molecules with different orbital structures was found owing to the coupling degree of intrinsic molecular resonance and photo-induced charge transfer. A sensitive detection of lycopene in beverage samples with a high recovery rate was finally realized by the BP/ZIF-67 composite substrate, which exhibited great potential in practical molecular selective recognition.
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