Synthesis, Characterization, and X-ray Crystal Structure Analysis of Zinc(II) Complex Based on 2-benzimidazolethiole

A novel mononuclear complex of the type [Zn(S-2-BIT)3(O-SO3)(CH3OH)2] (where 2-BIT = 2-benzimidazolethiole) was synthesized and its structure was investigated by elemental analysis, FT-IR spectroscopy, UV-Vis spectroscopy, and single crystal X-ray diffraction.The crystal structure of the complex show that, crystallizes in the triclinic P1 ̅ space group, with a=9.2946(13)Å, b= 10.1997(13) Å, c= 17.345(3) Å, β=105.494(7)օ , V= 1516.3(4)Å 3 , R1= 0.0316, wR2= 0.0843.In this complex, the distorted tetrahedral arrangement around the Zinc(II) atom is formed by three sulfur atoms from the 2-MBI ligand and one oxygen atom from the sulfate ion, and the crystal lattice structure of the complex also contains two uncoordinated methanol molecules that formed N-H ... O and O-H ... O intermolecular hydrogen bonds.