Intermolecular C–H⋯O and n → π* and short intramolecular σ → π* interactions in the molybdenum(0) tetracarbonyl complex of a very twisted 14-membered tetraazaannulene macrocyclic ligand: structural and computational studies

An interesting intermolecular n → π* interaction supported an intermolecular C–H⋯O interaction in a molybdenum tetracarbonyl complex of a substituted dibenzo-tetraazaannulene complex to consolidate the crystal packing in the solid state.