X射线吸收精细结构
催化作用
费托法
价(化学)
化学工程
原位
材料科学
化学
结晶学
选择性
有机化学
光谱学
量子力学
物理
工程类
作者
Qiang Chang,Ké Li,Chenghua Zhang,Ajin Cheruvathur,Lirong Zheng,Yong Yang,Yongwang Li
出处
期刊:Chemcatchem
[Wiley]
日期:2019-03-26
卷期号:11 (8): 2206-2216
被引量:14
标识
DOI:10.1002/cctc.201801807
摘要
Abstract Highly dispersed catalysts are widely used in industry and academia because of their large surface active sites. However, the predominant short‐range ordered structures in catalysts cannot be revealed by bulk characterization tools. The present study chooses a highly dispersed Fe−SiO 2 FTS catalyst as a research object and shows how X‐ray absorption fine structure (XAFS) helps to analyze the chemical information (iron composition, reduction degree, and iron valence) and structural information (coordinating atom and coordination number) of catalyst. The activation process of catalysts are detailedly studied under different atmospheres (CO, H 2 , or 2H 2 /CO) by using both ex‐situ and in‐situ XAFS. CO activation behaves most effective during the whole process and finally produces the highest content of active iron species compared with H 2 and 2H 2 /CO activation. The coordination number evolution of nearest Fe−O and Fe−C shells around Fe are put forward to understand the activation process. The present study demonstrates how XAFS elaborately reveals the phase transformations of the highly dispersed Fe−SiO 2 FTS catalyst.
科研通智能强力驱动
Strongly Powered by AbleSci AI