Hydrogen bond-directed encapsulation of metalloporphyrin into the microcages of zeolite imidazolate frameworks for synergistic biomimetic catalysis

In efforts to replicate the 3D model and desirable function of haemoglobin, the zeolite imidazolate framework (ZIF-8) was delineated for an ideal host matrix to accommodate custom-designed porphyrin molecules via hydrogen bonding.