聚吡咯
微分脉冲伏安法
检出限
钯
材料科学
水溶液
电化学
纳米复合材料
玻璃碳
单体
吡咯
循环伏安法
电极
核化学
高分子化学
复合材料
化学
聚合物
催化作用
有机化学
色谱法
物理化学
作者
M.R. Mahmoudian,Wan Jeffrey Basirun,Yatimah Alias
标识
DOI:10.1021/acs.iecr.6b00570
摘要
We report a facile synthesis of polypyrrole-coated palladium silver nanospherical (PdAg NSPs-PPy) composites via direct reduction of Pd2+ and Ag+ in the presence of pyrrole monomers from an aqueous solution of Pd(CH3COO)2, AgNO3, and NaOH. The nanocomposites were synthesized with different ratios of Pd and Ag (2:1, 1:1, and 1:2). X-ray diffraction shows that the Pd2+ and Ag+ were completely reduced to Pd and Ag, respectively, during the formation of PdAg NSPs-PPy. The modified glassy carbon electrode with the Pd2Ag1 NSPs-PPy demonstrated excellent electrochemical activity toward dopamine oxidation compared with the bare GCE, Pd1Ag1 NSPs-PPy, and Pd1Ag2 NSPs-PPy. From the differential pulse voltammetry results, the estimated limit of detection (S/N = 3) and limit of quantification (S/N = 10) for the linear segment (0.001–200 μM of dopamine) are 0.0258 and 0.0860 μM, respectively.
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