化学
甘露聚糖
特性粘度
多糖
粘度
酵母
粘度计
色谱法
流变学
生物利用度
生物化学
有机化学
聚合物
材料科学
复合材料
生物
生物信息学
作者
Ying Yang,Hongzhi Liu,Aimin Shi,Li Liu,Hui Hu,Qiang Wang
标识
DOI:10.1016/j.jconrel.2017.03.342
摘要
Mannans were extracted from S. cerevisiae, the rheological properties of mannan solutions were important in many industrial applications. In this paper, effects of mannans concentration, solution temperature, pH, salts and their concentrations on apparent viscosity were investigated. The conformational parameters of yeast mannans were determined by SEC-MALS-RI-DP. The Higiro’s 1 and Higiro’s 2 plots were obtained by capillary viscometry gave an intrinsic viscosity of 0.166 and 0.131 dl/g. The yeast mannans solution showed Newtonian flow behavior at all the tested concentrations. The apparent viscosity of yeast mannans solution decreased continuously with the temperature increase (25 °C–85 °C) at a given shear rate. The viscosity did not change within the pH values of 4.0–10.0, however, it increased when the pH decreased from 4.0 to 2.0. The viscosity decreased with addition of CaCl2 up to 10 mM and remained constant above this concentration. The conformational parameters (derived from [η] vs Mw and Rg vs Mw) showed yeast mannans existed as a sphere-like shape with many shorter branches. The special flow behavior and conformation of yeast mannans may make it preferable polysaccharide in food industry.
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