Photoactive Covalent Organic Frameworks for Catalyzing Organic Reactions

Abstract Because of their large surface areas, long‐range order, π‐π stacking interactions and hierarchically integrated building blocks, covalent organic frameworks (COFs) have attracted increasing attention. Recently, COFs have been regarded as promising heterogeneous photocatalysts, owing to their remarkable light‐harvesting and energy transition capabilities. The research progress of COFs in photocatalytic organic synthesis is summarized, such as preparation of imines through the oxidation of amines, selective oxidation of sulfides, oxidative hydroxylation of arylboronic acids, C−H bond activation, cyclization, asymmetric organic synthesis and so on. Finally, a perspective of the present challenges of photoactive COFs in organic transformations is given.