材料科学
热电效应
功勋
分析化学(期刊)
热重分析
差示扫描量热法
热导率
塞贝克系数
兴奋剂
溶胶凝胶
热电材料
电阻率和电导率
矿物学
纳米技术
化学工程
复合材料
光电子学
色谱法
热力学
化学
电气工程
物理
工程类
作者
Faisal Ghafoor,Bilal Ghafoor,Deok‐kee Kim,Muhammad Farooq Khan,M. Anis-ur-Rehman
标识
DOI:10.1016/j.jmrt.2023.01.154
摘要
In this paper, we reported the cerium (Ce) doped thermoelectric materials with composition Bi2−xRxTe3 (R = Ce, x = 0.0, 0.1, and 0.2), which were prepared by using different wet chemical methods. The selected synthesis methods that were used included a simplified sol-gel method (Without Water and Surfactants-WOWS) and the Composite Mediated Hydrothermal Method (CMHM). The structural analysis of the samples showed rhombohedral and hexagonal structures. In addition, the surface morphology revealed a flower-like structure for the synthesized samples. The thermal stability was determined using differential scanning calorimetry and thermogravimetric analysis. The electrical conductivity of the samples with a doping ratio of x = 0.1 showed maximum conductivity of (19.10 × 103 (S/cm))-WOWS; (9.10 × 103 (S/cm)) – (CMHM) as compared to than that of other samples (x = 0.0 and 0.2). Interestingly, the doping of Ce increased the Seebeck effect, which also increased the power factor. The power factor of the samples x = 0.1 was higher than that of the undoped samples, which had a magnitude of 12.30 μW/cm.K2 (WOWS) and 7.02 μW/cm.K2 (CMHM). Moreover, we measured the thermal conductivity of the samples using the Advantageous Transient Plane Source (ATPS) method. Therefore, we found the higher figure of merit (ZT) value (0.41) at x = 0.1, which was prepared using a simplified sol-gel method, which is among the highest values that was reported for Bi2−xRxTe3 at room temperature. Because of its potential applications this material has great interest as a thermoelectric material and chip cooling sensing.
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