材料科学
石墨烯
超级电容器
电容
纤维
氧化物
电解质
复合材料
复合数
化学工程
纳米技术
电极
冶金
化学
物理化学
工程类
作者
Junchen Chen,Xin Song,Fenglin Yang,Yang Li,Shunzhi Yang,Li Liao,Shuo Yin,Bingshu Guo,Zhilei Ma,Yuanfu Chen,Mingshan Wang,Xing Li,Xiaoyan Zhang
标识
DOI:10.1016/j.surfin.2023.103604
摘要
In this study, a composite graphene fiber was created using electrochemically exfoliated graphene oxide (EGO) and chemically oxidized graphene oxide (GO) through a simple wet spinning process. The incorporation of EGO sheets in the fiber forms a highly conductive network, significantly enhancing its conductivity. The optimized EGO/GO fiber exhibits both high areal capacitance (532 mF cm−2) and volumetric capacitance (103 F cm−3). Moreover, the EGO/GO composite fiber demonstrates superior capacitance retention and increased fiber length compared to the GO fiber. A solid-state device was also constructed by the optimized EGO/GO fiber using PVA/H2SO4 gel electrolyte which demonstrates excellent flexibility. And the as prepared solid-state fiber shaped supercapacitor demonstrates an areal capacitance of 246 mF cm−2 at a current density of 0.69 mA cm−2, while maintains 185 mF cm−2 at a current density of 34.7 mA cm−2 showcasing excellent rate performance.
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