材料科学
超级电容器
纳米复合材料
介电谱
电介质
三元运算
电解质
电极
化学工程
电容
电化学
纳米技术
光电子学
化学
计算机科学
工程类
物理化学
程序设计语言
作者
Muhammad Zarrar Khan,Iftikhar Hussain Gul,Mutawara Mahmood Baig,Muhammad Aftab Akram
标识
DOI:10.1016/j.electacta.2023.141816
摘要
Herein, a SnO2/MWCNTs/PANI nanocomposite was synthesized using a wet chemical approach which acts as a multifunctional electrode for supercapacitor and hydrogen evolution reaction. The dielectric properties were studied using the Maxwell-Wagner model of space charge polarization. The increasing dielectric constant indicated the suitability of synthesized NPs for telecommunication, electronics, and other high-frequency applications. The dependence of impedance and dielectric behavior on grains and grain boundaries was further investigated via impedance spectroscopy and complex electric modulus. Based on a 6 M KOH aqueous electrolyte, the SnO2/MWCNTs/PANI as an electrode material for supercapacitors displays a capacity of 211 C g−1 at 1 A g−1 and exhibits excellent cycling stability with a capacitance retention ratio of 98% after 5000 cycles at a current density of 2 A g−1. For hydrogen evolution reaction in 0.5 M KOH, SnO2/MWCNTs/PANI electrode achieves a benchmark of 10 mA cm−2 at overpotentials of 524 mV. The results reveal that the SnO2/MWCNTs/PANI nanocomposite act as multifunctional material that can be used for both energy storage and conversion.
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