Graphdiyne: A New Carbon Allotrope for Electrochemiluminescence

Abstract Graphdiyne (GDY), a well‐known 2D carbon allotrope, demonstrates increasing fantastic performance in various fields owing to its outstanding electronic properties. Owing to its unique properties, electrochemiluminescence (ECL) technology is one powerful tool for understanding fundamental questions and for ultrasensitive sensing and imaging. Here, we firstly find that GDY without any functionalization or treatment shows a strong ECL emission with potassium persulfate (K 2 S 2 O 8 ) as coreactant, which is totally different with other carbon allotropes. Mechanistic study indicates that the ECL emission of GDY is generated by the surface state transition. Interestingly, ECL is generated at 705 nm in the near infrared region with an ECL efficiency of 424 % compared to that of Ru(bpy) 3 Cl 2 /K 2 S 2 O 8 . The study demonstrates a new character of GDY in ECL investigation and sets the stage for the development of GDY for emerging applications, including imaging and light‐emitting devices.