Activation of Persulfate by Irradiated Magnetite: Implications for the Degradation of Phenol under Heterogeneous Photo-Fenton-Like Conditions

We show that phenol can be effectively degraded by magnetite in the presence of persulfate (S2O82–) under UVA irradiation. The process involves the radical SO4–•, formed from S2O82– in the presence of FeII. Although magnetite naturally contains FeII, the air-exposed oxide surface is fully oxidized to FeIII and irradiation is required to produce FeII. The magnetite + S2O82– system was superior to the corresponding magnetite + H2O2 one in the presence of radical scavengers and in a natural water matrix, but it induced phenol mineralization in ultrapure water to a lesser extent. The leaching of Fe from the oxide surface was very limited, and much below the wastewater discharge limits. The reasonable performance of the magnetite/persulfate system in a natural water matrix and the low levels of dissolved Fe are potentially important for the removal of organic contaminants in wastewater.