复合数
硫黄
化学
材料科学
阴极
碳纤维
化学工程
锂(药物)
锂硫电池
电化学
无机化学
电极
有机化学
复合材料
物理化学
内分泌学
工程类
医学
作者
Yufei Zhang,Jing Feng,Fei Lv,Huan Xie,Yu Ma,Bowen Zhu,Tao Jiang,Li Chen,Zhaolin Liu
标识
DOI:10.1016/j.susmat.2021.e00346
摘要
MoS3 is in situ grown on sulfur carbon composite (S/C-MoS3) surface by chemical oxidative reaction of (NH4)2MoS4. Based on the synergistic role of porous carbon and polar MoS3 with sulfur-like characteristic, polysulfides are effectively anchored and shuttle effect is greatly reduced. In particular, 10 wt% MoS3 bridged S/C composite exhibits the best electrochemical performance. After 100 cycles at 0.2C, the discharge specific capacity remains 727.6 mA h g−1, and the capacity retention rate is 59.0%. When cycling 300 times at 1C, the capacity is still maintained at 546.9 mA h g−1, and the coulomb efficiency is around 97.0%. The results show that MoS3 effectively improves the cyclic property of S/C composite for lithium‑sulfur battery.
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