加氢脱氧
催化作用
解聚
沸石
木质素
化学
产量(工程)
烧焦
双金属片
溶剂
镍
铜
有机化学
无机化学
核化学
材料科学
选择性
热解
冶金
作者
Lingdong Kong,Chunze Liu,Jian Gao,Yuanyuan Wang,Liyi Dai
标识
DOI:10.1016/j.biortech.2019.01.015
摘要
The alcoholysis of Kraft lignin was catalyzed by bimetallic Ni-Cu supported on H-Beta, HZSM-5, MAS-7, MCM-41 and SAPO-11 zeolite materials in isopropanol solvent. Results showed that a higher bio-oil yield of 98.80 wt% and monomer yield of 50.83 wt% without obvious char were achieved at 330 °C for 3 h over Ni-Cu/H-Beta catalyst. Isopropanol was found to be more effective in H2 generation and facilitated to the hydrodeoxygenation of lignin-derived phenolic compounds. Moreover, the composition of liquid products was also influenced by the acidity and pore structure of catalyst. The superior cycloalkanes yield was produced over Ni-Cu/H-Beta with larger pore size and more acidity. In contrast, a large number of cyclic ketones/alcohols and alkanes were obtained over other zeolites supported catalysts with smaller pore size and less acid content. Besides, the temperature, time and solvent effect on the lignin depolymerization were also researched.
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