Synthesis of C25- and C26-Steroid Carboxylic Acids from C22-Steroids Using Nickelacycles as Propionic and Butyric Acid Equivalents
化学
丁酸
类固醇
羧酸
等价物
有机化学
立体化学
药物化学
生物化学
激素
作者
R. Fischer,Bruno Schönecker,Dirk Walther
出处
期刊：Synthesis [Thieme Medical Publishers (Germany)] 日期：1993-01-01卷期号：1993 (12): 1267-1270被引量：16
标识
DOI：10.1055/s-1993-26040
摘要
C25- and C26 -steroid carboxylic acids as well as their methyl esters with different rings A and B were synthesized with good to excellent yields from C22 -iodides 1 using the nickelacycles 2a and 2b as propionic and butyric acid equivalents.
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