甲脒
钙钛矿(结构)
材料科学
微观结构
相(物质)
结构精修
格子(音乐)
制作
杂质
化学工程
结晶学
晶体结构
复合材料
化学
物理
医学
替代医学
有机化学
病理
声学
工程类
作者
Chuwu Xing,Qiaoliang Bao,Shanjing Liu,Xuelei Chu,Fei Lü,Lian Zhang,Liping Yu,Tianjin Zhang,Duofa Wang
出处
期刊:Solar RRL
[Wiley]
日期:2023-08-20
卷期号:7 (21)
标识
DOI:10.1002/solr.202300434
摘要
Lattice strain is often regarded as an important factor affecting the stability of organic–inorganic hybrid perovskite solar cells, but the current understanding on the origin of the strain is still unclear. Herein, the microstructure of formamidinium perovskite is analyzed by the Rietveld refinement method to reveal the origin of its microstrain. It is found that there is a lattice mismatch between the α‐phase perovskite and the δ‐phase impurity during the fabrication process, which generates strong microstrain in perovskite film. Moreover, the strain also exacerbates the aging process of formamidinium perovskite. By introducing Cs ions, the lattice mismatch of α‐phase and δ‐phase perovskites is reduced, thereby reducing the microstrain of perovskites and improving the device performance.
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