脂肪酶
油酸
生物催化
化学
生物柴油
微载波
环境友好型
乳状液
有机化学
化学工程
胺气处理
催化作用
生物化学
酶
离子液体
生物
生态学
工程类
细胞
作者
Lei Tian,Panpan Zhao,Xue Li,Zafar Ali,Xiangjie Li,Baoliang Zhang,Hepeng Zhang,Qiuyu Zhang
出处
期刊:Chemcatchem
[Wiley]
日期:2016-07-22
卷期号:8 (16): 2634-2641
标识
DOI:10.1002/cctc.201600413
摘要
Abstract Raspberry‐shaped microparticles with adjustable protrusions and functional groups were synthesized and applied as carriers for the immobilization of lipase. The structural advantages of the raspberry‐shaped microcarriers with immobilized lipase (RM‐IL) are not only that the protrusions are constructed to play the role of a spacer arm, but the block structure enhances the bioactivity of lipase at the oil–water interface. The activation method used for the carrier has a significant effect on the performance of immobilized lipase. RM‐IL prepared by carboxylic acid activation has a 3.5‐fold increase of activity compared with that from amine activation and generates a fourfold increase of protein bound to 164 mg g −1 of carrier. Finally, RM‐IL is used as an environmentally friendly and high‐efficiency biocatalyst to catalyze the esterification of oleic acid for biodiesel under mild conditions, and the conversion can reach up to 82.1 %. Above all, raspberry‐shaped microcarriers prepared by an improved seed emulsion polymerization have prospects for industrialization.
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