差示扫描量热法
玻璃化转变
材料科学
乙二醇
高分子化学
傅里叶变换红外光谱
动态力学分析
化学工程
PEG比率
增塑剂
极限抗拉强度
乳酸
聚合物
复合材料
遗传学
财务
生物
细菌
工程类
经济
物理
热力学
作者
Kyung‐Man Choi,Myeon‐Cheon Choi,Dong-Hun Han,Taesung Park,Chang‐Sik Ha
标识
DOI:10.1016/j.eurpolymj.2013.05.027
摘要
Poly(lactic acid) (PLA) was grafted by low molecular weight acrylated-poly(ethylene glycol) (PEG) via a reactive blending to improve its plasticity. The acrylated-PEG grafted onto PLA was confirmed by the result of nuclear magnetic resonance (NMR) spectra, Fourier transform infrared (FTIR) spectra, wide-angle X-ray diffraction (WAXD) patterns as well as solvent extraction. The properties of the grafted PLAs (PLEAs) were investigated through tensile testing (UTM), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and hydrolytic degradable analysis. The glass transition temperature (Tg) of the PLEAs significantly decreased by more than 20 °C and the glass transition exhibits at a broad temperature range between 15 and 56 °C. The Young’s modulus of PLA was lowered by 66% from 1.2 GPa to 0.4 GPa, while the elongation at break of PLA was increased by 380% from 4.7% to 17.9%.
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