重氮
化学
有机硼化合物
硼酸
有机化学
硼
组合化学
作者
Huan Li,Yan Zhang,Jianbo Wang
出处
期刊:Synthesis
[Georg Thieme Verlag KG]
日期:2013-10-10
卷期号:45 (22): 3090-3098
被引量:38
标识
DOI:10.1055/s-0033-1340041
摘要
The transition-metal-free reactions of diazo compounds with organoboron compounds are reviewed. This type of reaction provides an alternative approach for the formation of C–C, C–B, and C–Si bonds. Moreover, by using tosylhydrazones as diazo compound precursors and boronic acids/esters as the boron substrates, this type of reaction becomes of practical use in organic synthesis. This short review covers the recent developments of this area with an introduction to the historical background. 1 Introduction 2 Reaction of Diazo Compounds with Organoboranes 3 Reactions of Diazo Compounds with Boronic Acids and Related Organoborons 4 Reaction of Diazo Compounds with Boronic Esters 5 Concluding Remarks
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