成核
过饱和度
格式化
阳极
材料科学
电化学
化学物理
化学工程
电极
曲率
纳米技术
化学
催化作用
物理化学
有机化学
工程类
几何学
数学
作者
Haixia Ren,Martin A. Edwards,Yufei Wang,Henry S. White
标识
DOI:10.1021/acs.jpclett.9b03898
摘要
CO2 is an anodic product of many liquid fuel cells. The nucleation of CO2 nanobubbles during cell operation may block the transport of the fuel to the anode, lowering the overall conversion efficiency. Herein, we report the controlled formation of individual CO2 nanobubbles at Pt nanoelectrodes via the electrooxidation of formate. The electrochemical data are used to extract key parameters of CO2 gas nucleation. We determine that CO2 bubbles nucleate when the concentration of CO2 at the Pt electrode is greater than ∼0.6 M, corresponding to supersaturation of ∼18. The critical nucleus required for the formation of a CO2 bubble is measured to have a radius of curvature of ∼100 nm, a contact angle of 173°, and contains ∼70 CO2 molecules.
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