Regulable in-situ autoredox for anchoring synergistic Ni/NiO nanoparticles on reduced graphene oxide with boosted alkaline electrocatalytic oxygen evolution

To develop ideal alternatives to noble metal catalysts, transition metal catalysts supported on graphene have been receiving extensive attention in the field of electrochemical energy. In this work, using graphene oxide (GO) and nickel formate as precursors, Ni/NiO synergistic nanoparticles with regulable composition are anchored on reduced graphene oxide (RGO) to prepare Ni/NiO/RGO composite electrocatalysts through in-situ autoredox. Thanks to the synergistic effect of Ni3+ active sites and Ni electron donors, the as-prepared Ni/NiO/RGO catalysts exhibit efficient electrocatalytic oxygen evolution performance in 1.0 M KOH electrolyte. The optimal sample has an overpotential of only 275 mV at a current density of 10 mA cm-2 and a small Tafel slope of 90 mV dec-1, which are very comparable to those of commercial RuO2 catalyst. Additionally, the catalytic capacity and structure remain stable after 2000 cyclic voltammetry cycles. For the electrolytic cell assembled with the best-performing sample as anode and commercial Pt/C as cathode, the current density can reach 10 mA cm-2 at a low potential of 1.57 V and remains stable after 30 h of continuous work. It would be expected that the as-developed Ni/NiO/RGO catalyst with high activity should have broad application prospects.