Revisiting Iodide Species Transformation in Peracetic Acid Oxidation: Unexpected Role of Radicals in Micropollutants Decontamination and Iodate Formation

Peracetic acid (PAA) is an alternative disinfectant for saline wastewaters, and hypohalous acids are typically regarded as the reactive species for oxidation and disinfection. However, new results herein strongly suggest that reactive radicals instead of HOI primarily contributed to decontamination during PAA treatment of iodine-containing wastewater. The presence of I