Cover Picture: Soft Alloys Constructed with Distinct Mesoatoms via Self‐Sorting Assembly of Giant Shape Amphiphiles (Angew. Chem. Int. Ed. 19/2022)

Metal alloy superlattices with large volume asymmetry were constructed based on self-sorting assembly of binary giant shape amphiphiles, as reported by Zebin Su, Stephen Z. D. Cheng et al. in their Research Article (DOI: 10.1002/anie.202200637). MgZn2, NaZn13 and CaCu5 superlattices were observed in soft matters, and the thermodynamic origin of their formation was quantitatively analyzed.